銆銆榪戞湡錛屼腑鍥界瀛﹂櫌鍚堣偉鐗╄川縐戝鐮旂┒闄㈠尰瀛︾墿鐞嗕笌鎶鏈腑蹇冨厜璋辮川璋辯爺絀跺鍦ㄧ嚎璐ㄨ氨媯嫻嬫柊鍘熺悊銆佹柊鏂規硶鐮旂┒鍙栧緱榪涘睍錛屽彂灞曠殑璐ㄥ瓙鎻愬彇鍙嶅簲璐ㄨ氨錛圥roton Extraction Reaction Mass Spectrometry, PER-MS錛夋柊鎶鏈紝瀹炵幇浜嗗鐥曢噺鏈夋満鍜屾棤鏈哄寲鍚堢墿鐨勫悓鏃剁洃嫻嬨傛欏圭爺絀跺伐浣滃彂琛ㄥ湪銆婅川璋卞浗闄呮潅蹇椼嬶紙International Journal of Mass Spectrometry錛変笂銆?
銆銆闀挎湡浠ユ潵錛屼互璐ㄥ瓙杞Щ鍙嶅簲璐ㄨ氨錛圥TR-MS錛変負浠ｈ〃鐨勫厛榪涘湪綰胯川璋辨妧鏈紝鍦ㄧ幆澧冦佺敓鐗┿佸尰鐤楀仴搴楓佸叕鍏卞畨鍏ㄧ瓑棰嗗煙鍙戞尌鐫閲嶈浣滅敤錛屼負鐥曢噺鎸ュ彂鎬ф湁鏈虹墿錛圴OC錛夌殑蹇熷畾閲忔嫻嬫彁渚涗簡楂樼伒鏁忔妧鏈墜孌點侾TR-MS鐨勫伐浣滃師鐞嗘槸閫氳繃姘存斁鐢靛埗澶囩殑鍙嶅簲紱誨瓙H3O 涓庤嫻嬬墿璐╒OC涔嬮棿鐨勮川瀛愯漿縐誨弽搴旓紝灝哣OC杞寲涓?VOC)H 錛屼粠鑰屽疄鐜癡OC鐨勭瀛愬寲鍜屽悗緇殑璐ㄨ氨鎺㈡祴銆傛棭鍦?008騫達紝鍏夎氨璐ㄨ氨鐮旂┒瀹ょ鐮斾漢鍛樼爺鍒朵簡鎴戝浗棣栧彴PTR-MS浠櫒錛屽茍鍦ㄥ浗闄呬笂鐜囧厛灝嗚鎶鏈敤浜庣偢鑽佸尰鐤楀櫒姊版憾鍓傛畫鐣欏拰鏉鑿屽墏孌嬬暀浠ュ強鏄撳埗姣掑搧鐨勫揩閫熸嫻嬶紝鐮旂┒瀹や富浠誨偍鐒板崡鐮旂┒鍛樺茍鍙楅個緙栧啓浜哅ass Spectrometry Handbook錛圝ohn Wiley & Sons, 2012錛変腑鐨凱TR-MS绔犺妭銆備絾鏄紝鐢變簬H3O 涓庢棤鏈哄寲鍚堢墿鍑犱箮涓嶅彂鐢熷弽搴旓紝鍥犳錛屼互H3O 涓哄弽搴旂瀛愮殑PTR-MS鎶鏈嫻嬩笉浜嗘棤鏈哄寲鍚堢墿銆?
銆銆涓轟簡瑙ｅ喅榪欎釜闂錛屽厜璋辮川璋辯爺絀跺縐戠爺浜哄憳鍙﹁緹鏂板緞錛岄氳繃姘存斁鐢墊垚鍔熷埗澶囦簡璐熺瀛怬H-錛屽埄鐢ㄥ弽搴旂瀛怬H-涓嶸OC涔嬮棿鐨勮川瀛愬弽鏂瑰悜杞Щ鍙嶅簲錛屽嵆璐ㄥ瓙鎻愬彇杞Щ鍙嶅簲錛圥ER錛夛紝灝嗚嫻嬬墿璐╒OC杞寲涓?VOC-H)-錛屼粠鑰屽疄鐜癡OC鐨勭瀛愬寲鍜屽悗緇殑璐ㄨ氨鎺㈡祴錛涙洿涓洪噸瑕佺殑鏄紝OH-鍙互涓庢棤鏈哄寲鍚堢墿渚嬪CO2鍙戠敓鍙嶅簲錛屽皢鏃犳満鐗╄漿鍖栦負紱誨瓙渚嬪CO2OH-銆傚洜姝わ紝鏂板彂灞曠殑浠H-浣滀負鍙嶅簲紱誨瓙鐨勮川瀛愭彁鍙栧弽搴旇川璋盤ER-MS錛屼笉浣嗚兘媯嫻嬫湁鏈虹墿錛岃屼笖涔熷彲浠ユ嫻嬫棤鏈虹墿銆?
銆銆璇ラ」鐮旂┒鎻愬嚭鐨凱ER-MS鎶鏈紝涓嶄絾涓板瘜浜嗗湪綰胯川璋卞唴瀹癸紝鑰屼笖涔熶負鐥曢噺鏈夋満/鏃犳満鐗╃殑鍚屾椂媯嫻嬶紝鎻愪緵浜嗕竴縐嶆柊鎵嬫銆傜浉鍏蟲妧鏈凡緇忕敵鎶ヤ簡鍥藉鍙戞槑涓撳埄銆?
璐ㄥ瓙鎻愬彇鍙嶅簲璐ㄨ氨錛圥ER-MS錛夊師鐞嗙ず鎰忓浘
