?.Ҏ(gu)出限
|
元素 |
ICPMS?span> |
AA?span> |
||
|
仪器出限 |
Ҏ(gu)出限 (mg/kg) |
仪器出限 |
Ҏ(gu)出限 (mg/kg) |
|
|
Pb |
0.003 ng/mL |
0.0003 |
0.200ng/mLQ石墨炉法） |
0.0200 |
|
Cd |
0.002 ng/mL |
0.0002 |
0.020ng/mLQ石墨炉法） |
0.0020 |
|
As |
0.012 ng/mL |
0.0012 |
0.080 ng/mLQ氢化物法） |
0.0080 |
|
Hg |
0.002 ng/mL |
0.0002 |
0.130 ng/mLQ冷蒸汽吸收法） |
0.0130 |
|
Cu |
0.064 ng/mL |
0.0064 |
0.012μg/mLQ火焰法Q?/span> |
1.2000 |
使用ICPMS-2030和AA-7000定5U重金属?qing)有宛_素，限均低?/span>0212通则要求?/span>
Q二Q农药残?/span>
中药材生产种植过E中怋用杀虫剂、除草剂、生长调节剂Q以辑ֈ消除病虫宻I提高产量的目的。中国常用的农药主要为有机氯cR有机磷cR}基甲酔Rcd拟除虫菊(qing)酯类?212通则规定以下33U禁用农药不得检出?/span>2341农药D留量测定法标明了方法定量限?/span>
药材?qing)饮片（植物c）33U禁用农药定量限?qing)推荐方?
|
~号 |
农药名称 |
D留?/span> |
定量限（mg/kgQ?/span> |
推荐Ҏ(gu) |
|
1 |
甲胺?/span> |
甲胺?/span> |
0.05 |
LCMSMS |
|
2 |
甲基对硫?/span> |
甲基对硫?/span> |
0.02 |
GCMSMS |
|
3 |
对硫?/span> |
对硫?/span> |
0.02 |
GCMSMS |
|
4 |
久效?/span> |
久效?/span> |
0.03 |
GCMSMS/LCMSMS |
|
5 |
|
|
0.05 |
LCMSMS |
|
6 |
六六?/span> |
-六六六?/span>β-六六六?/span>-六六六?/span>δ-六六六之?/span> |
0.1 |
GCMSMS |
|
7 |
滴滴?/span> |
4,4'-滴滴涕?/span>2,4'-滴滴涕?/span>4,4'-滴滴伊?/span>4,4'-滴滴滴之?/span> |
0.1 |
GCMSMS |
|
8 |
杀虫脒 |
杀虫脒 |
0.02 |
GCMSMS/LCMSMS |
|
9 |
除草?/span> |
除草?/span> |
0.05 |
GCMSMS |
|
10 |
艾氏?/span> |
艾氏剂与狄氏剂之?/span> |
0.05 |
GCMSMS |
|
11 |
狄氏?/span> |
|||
|
12 |
苯线?/span> |
苯线及(qing)其氧cM物（砜、亚砜）之和Q以苯线C?/span> |
0.02 |
GCMSMS/LCMSMS |
|
13 |
地虫磷 |
地虫磷 |
0.02 |
LCMSMS |
|
14 |
线?/span> |
线?/span> |
0.02 |
LCMSMS |
|
15 |
蝇毒?/span> |
蝇毒?/span> |
0.05 |
GCMSMS/LCMSMS |
|
16 |
治螟?/span> |
治螟?/span> |
0.02 |
GCMSMS/LCMSMS |
|
17 |
特丁磷 |
特丁磷?qing)其氧类似物Q砜、亚砜）之和Q以特丁磷表示 |
0.02 |
GCMSMS/LCMSMS |
|
18 |
氯磺?/span> |
氯磺?/span> |
0.05 |
LCMSMS |
|
19 |
隆 |
隆 |
0.05 |
LCMSMS |
|
20 |
甲磺?/span> |
甲磺?/span> |
0.05 |
LCMSMS |
|
21 |
甲拌?/span> |
甲拌及(qing)其氧cM物（砜、亚砜）之和Q以甲拌C?/span> |
0.05 |
GCMSMS/LCMSMS |
|
22 |
甲基异柳?/span> |
甲基异柳?/span> |
0.05 |
GCMSMS/LCMSMS |
|
23 |
内吸?/span> |
内吸?/span> |
0.05 |
GCMSMS/LCMSMS |
|
24 |
克百?/span> |
克百威及(qing)3-基克百威之和，以克癑֨表示 |
0.05 |
LCMSMS |
|
25 |
涕灭?/span> |
涕灭威及(qing)其氧cM物（砜、亚砜）之和Q以涕灭威表C?/span> |
0.1 |
LCMSMS |
|
26 |
灭线?/span> |
灭线?/span> |
0.02 |
GCMSMS/LCMSMS |
|
27 |
氯唑?/span> |
氯唑?/span> |
0.01 |
LCMSMS |
|
28 |
水胺磷 |
水胺磷 |
0.05 |
GCMSMS/LCMSMS |
|
29 |
丹 |
-丹?/span>β-丹?qing)硫丹硫酔R之和 |
0.05 |
GCMSMS |
|
30 |
氟虫?/span> |
氟虫腈、氟甲腈、氟虫腈砜、氟虫腈亚砜之和Q以氟虫腈表C?/span> |
0.02 |
GCMSMS |
|
31 |
三氯杀螨醇 |
三氯杀螨醇Q?/span>o,p?异构体和p,p?异构体之和） |
0.2 |
GCMSMS |
|
32 |
环?/span> |
环?/span> |
0.03 |
LCMSMS |
|
33 |
甲基环?/span> |
甲基环?/span> |
0.03 |
GCMSMS |
