Comparison and Thermodynamic Analysis of Crystallinity of noncrosslinking and Crosslinking Fluorinated Acrylate Copolymers Films
作者：Chen Huiqin,Wu Bing,Cai ZhiQi,Pi Pihui,Wen Xiufang,Zheng Dafeng,Cheng Jiang,Yang Zhuoru
關(guān)鍵字：Fluorinated copolymer, Crystallinity, Thermodynamic analysis, X-ray diffraction
論文來源：會議
具體來源：ADVANCED MATERIALS, PTS 1-4叢書: Advanced Materials Research 卷: 239-242 頁: 1391-1395
發(fā)表時間：2011年
In this manuscript two different fluorinated acrylate copolymers films, one was non-crosslinking Stearyl acrylate/2-(perfluorooctyl) ethyl methacrylate (SA/FOEMA) and another was cross-linked SA/2-hydroxyethyl methacrylate(HEMA)/FOEMA/hexamethylene diisocyanate trimers (N3300), were prepared and their crystallinities were investigated by means of X-ray diffraction (XRD) and differential scanning calorimetry (DSC). It can be shown from the XRD results that the value of crystallinities of SA/FOEMA and SA/HEMA/FOEMA/N3300 copolymer were 80.95% and 84.02%, respectively. Based on DSC curves and theoretical thermodynamic analysis, it is indicated that crosslinking can improve crystallinity of copolymer composed of SA and FOEMA.