[Small] Fabrication of Patterned Polymer Brushes on Chemically Active Surfaces by in situ Hydrogen Bond Mediated Attachment of an Initiator
作者：Tao Chen, Debby P. Chang, and Stefan Zauscher
關(guān)鍵字：Polymer Brush, Patterning, Hodrogen Attachment
論文來源：期刊
具體來源：Small, 2010, 14, 1504-1508, Inside cover story
發(fā)表時(shí)間：2010年
The cover picture shows a 3D AFM topographic image of PNIPAAM brushes micropatterned on a COOH-functionalized, polyacrylic acid (PAA) polymer brush substrate. In this novel patterning approach, the brush substrate is first patterned with an atom transfer radical polymerization (ATRP) initiator silane, which attaches by hydrogen bond formation to the 
COOH species at the top of the PAA brush substrate; the resulting pattern is then amplified by ATRP. Notably this approach does not rely on the chain-terminal, “l(fā)iving” initiator of the substrate brush, which can suffer from low re-initiation efficiency, and thus provides an exciting method for synthesizing long graft or block copolymer brushes on polymeric substrates. The relative heights of the substrate polymer brush and the patterned block/graft polymer brushes can be tailored by controlling the ATRP reaction conditions.
This inside cover story <![endif]-->featured on materials science news site MaterialsViews.com, http://www.materialsviews.com/details/news/748169/Brushes_ Grown_on_Brushes.html
