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Ordered macroporous films from self-assembly of two-armed polymer with a crown ether core
作者:Fu, J.; et al.
關鍵字:macroporous films, self-assembly, two-armed polymer
論文來源:期刊
具體來源:Polymer, 2004, 45, 7389-7394.
發表時間:2004年

Highly ordered honeycomb-like macroporous films were obtained via self-assembly of a two-armed polymer with a crown ether core under controlled conditions. A possible mechanism is speculated, primarily based on the strong affinity between the crown ether cores. The pore size and arrangement are sensitive to the solvent evaporation rate and the solution concentration. Upon spontaneous drying, the pore diameter (D) depends on the concentration (c) by a relation of D = 518 c -0.610.

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