NiCoO2 nanosheets interlayer network connected in reduced graphene oxide and MXene for high-performance asymmetric supercapacitors
作者：Changhai Li, Guohua Jiang*, Tianqi Liu, Zhiyong Zeng, Pengfei Li, Ruofan Wang, Xueya Zhang
關鍵字：Reduced graphene oxide; MXene; Supercapacitor; NiCoO2; Electrochemical properties
論文來源：期刊
具體來源：Journal of Energy Storage
發表時間：2022年
Abstract: The composite electrode materials (rGO/MXene@NiCoO2) have been prepared by tightly wrapping of reduced graphene oxide (rGO) and MXene to NiCoO2 nanosheets. The specific capacitance of rGO/MXene@NiCoO2-5wt% is 1614 F·g-1 at 0.5 A g-1, maintains at 1257.5 F·g-1 when increasing the current density to 10 A·g-1. And the capacitance retention is 77.29% even after 10,000 cycles. It is attributed to the special interlayer network structure of the rGO/MXene@NiCoO2 composite, which promotes more ion intercalation/deintercalation and improves the structure stability. An asymmetric supercapacitor (ASC) is assembled using rGO/MXene@NiCoO2 as the positive electrode and rGO/MXene as the negative electrode, respectively. The maximum energy density is 45.15 Wh·kg-1 and the power density is 394.52 W·kg-1. After 10,000 cycles with current density at 5 A·g-1, the capacity retention rate is 82.69%. These results demonstrate the potential application of rGO/MXene@NiCoO2 composite networks as electrode materials for supercapacitors.