Azo-Linked Porous Organic Polymers: Robust and Time-Efficient Synthesis via NaBH4-Mediated Reductive Homocoupling on Polynitro Monomers and Adsorption towards Aniline in Water
作者：Jin-Xiu Zhou, Xian-Sheng Luo, Xiangxiang Liu*, Yan Qiao, Pengfei Wang, David Mecerreyes, Nicolas Bogliotti, Shi-Lu Chen and Mu-Hua Huang*
關鍵字：Azo-POP-1, Azo-POP-2, Azo-POP-3; Porous Organic Polymers; Facile prepareation; Adsorptioin; Reductive Coupling
論文來源：期刊
具體來源：Journal of Materials Chemistry A
發表時間：2018年
Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of those materials. In this work, we show a robust and time-efficient synthetic method of azo-linked porous organic polymers named Azo-POPs based on a NaBH4-mediated reductive coupling polymerization on well-known polynitro monomors. Azo-POPs were found to have high Brunauer–Emmett–Teller (BET) surface area and potential for aniline adsorption. Interestingly, Azo-POP-1 showed adsorption towards aniline as high as 1059.68 mg.g-1 at 293K, which outperformed absorbent materials reported in literature.