Flexible porous organic polymers with 1,2-diol subunits favoring the high loading of Pd nanoparticles
作者：Zhi-Cun Wang, Boya Kuang, Hanyuan Chen, Nicolas Bogliotti, Ran Guo, Yan Liu, Jin-Xiu Zhou*, Mu-Hua Huang*
關鍵字：Flexible POPs, 1,2-diol, loading of Pd NP
論文來源：期刊
具體來源：Nanoscale, 2025, 17, 9914-9919.
發表時間：2025年
In recent years, the flexibility of porous organic polymers has demonstrated very unique properties during their applications. This paper reports a novel soluble porous polymer (named BIT-POP-75 and BIT-POP-75-OH) with 1,2-diketone and 1,2-diol subunits in the flexible polymer chain using contorted subunits. The solubility of the porous polymer and the flexible chelating 1,2-diol moiety facilitates the high loading and uniform dispersion of Pd nanoparticles to give the catalyst Pd@BIT-POP-75-OH, which shows high efficiency (kapp = 0.965 min?1) for
the catalytic reduction of 4-nitrophenol with good recyclability (10 cycles).