Synthesis, crystal structure and Hirshfeld surfaces of a Cu-II complex with an ICL670-related ligand
作者：Yang-Hui Luo, Jian Xu and Bai-Wang Sun*
關鍵字：copper complex, crystal structure, ICL670 analogue, Hirshfeld surface, antimalarials, chelators
論文來源：期刊
發(fā)表時間：2012年
The complex [Cu2(μ?L)2].DMF (L = 2, 2’-[1-(2, 4, 6-trichlorophenyl)-1H-1, 2, 4-triazole-3, 5-diyl] diphenolate) has been prepared and its structure determined. The two CuIIions are four-coordinated in a planar structure, with the DMF molecule wrapped in the “wings” of ligand L. Hirshfeld surface and fingerprint plots reveal that the complex structure is stabilised mainly by H···H, C–H…Cl, C–H···π, π···π and lone-pair···π (C–Cl) intermolecular interactions.