Smart Self-Assemblies Based on Surfactant-encapsulated Photoresponsive Polyoxometalate Complex
作者：Yi Yan, Huanbing Wang, Bao Li, Guangfeng Hou, Zhendong Yin, Lixin Wu,* and
關(guān)鍵字：isomerization，photochemistry，polyoxometalates，self-assembly，supramolecular chemistry
論文來(lái)源：期刊
具體來(lái)源：Angew. Chem. Int. Ed. 2010, 49, 9233-9236.
發(fā)表時(shí)間：2010年
Smart POMs: A surfactant-encapsulated organic-grafted polyoxometalate (POM) is synthesized by grafting a photoresponsive azobenzene group to an Anderson-type POM cluster. Self-assemblies of the hybrid complexes exhibit photocontrolled reversible aggregation and morphological change as a result of photoisomerization-induced structural alternation (see figure).