Improving the flame resistance and thermal conductivity of ethylene-vinyl acetate composites by incorporating hexachlorocyclotriphosphazene-modified graphite and carbon nanotubes.
作者：張勝，田瑩，谷曉昱，唐武飛，孫軍*
關鍵字：the flame resistance and thermal conductivity；ethylene-vinyl acetate composites
論文來源：期刊
發表時間：2017年
Graphite has been regarded as a promising additive for improving the fire safety and thermalconductivity (TC) of polymers. In this article, graphite was modified by grafting with hexachlorocyclotriphosphazene to prepare a novel modified graphite oxide (M-GO). M-GO in association with multiwalled carbon nanotubes (MWNT) were introduced into ethylene-vinyl acetate (EVA) by melt compounding to prepare bifunctional composites with excellent fire resistance and TC. The flammability of the EVA compositeswas characterized by limiting oxygen index (LOI), vertical burning (UL-94), and cone calorimeter test. The results showed that the sample containing 18% M-GO and 2% MWNT achieved the maximal LOI value of 31.6%, passedthe UL-94 V-0 rating, and significantly decreased the peak heat release rate from 1383.7 kW/m2of neat EVA to 558.3 kW/m2. The TC of the EVA composites was characterized by a TC analyzer, and the results showed that thepresence of M-GO and MWNT could significantly increase the TC by the formation of more efficient thermaltransfer pathways. The thermal behaviors of EVA composites and the morphologies of residues were characterized and the possible mechanisms were also proposed. © 2017 Society of Plastics Engineers.