[Progress in Chemistry] Dynamic and Reversible Intelligent Systems Regulated by Chemical Oscillating Reactions
作者：B.Yan, H.W.Zhou,* P.Xie, X.L.Jin, A.J.Ma, W.X.Chen,
關鍵字：hemical oscillating reaction; dynamic and reversible interaction; dynamic covalent bond; hostguest interaction; coordination interaction; ionic interaction
論文來源：期刊
具體來源：Progress in Chemistry, 2017, 29, 740-749.
發(fā)表時間：2017年
Dynamic and reversible interaction is one of important tools for constructing intelligent material systems with controllability and adjustability． However， most of the intelligent systems based on dynamic and reversible interactions only respond to “on / off”transition of external stimuli， including light， heat， solvent，pH， etc．， instead of automatic regulation． The development of chemical oscillating reactions and self-oscillating polymer materials provides an important idea for the construction of self-regulated intelligent systems． We introduce dynamic and reversible intelligent systems ( DＲIS ) regulated by chemical oscillating reactions， including autonomous aggregation /disaggregation nanoparticle systems， autonomous assembly /disassembly amphiphilic molecule systems， autonomous assembly /disassembly hydrogel systems， autonomous molecular shuttle systems and autonomous fluorescent oscillation systems， which are constructed base on dynamic and reversible interactions， such as dynamic covalent bonds， host-guest interactions， coordination interactions， ionic interactions and intermolecular interactions． Finally， we prospect the future investigation and development of DＲIS regulated by chemical oscillating reactions．