Synergetic photo-epoxidation of propylene with molecular oxygen over bimetallic Au-Ag/TS-1 photocatalysts
作者：Li, NX (Li, Naixu)[ 1 ] ; Yang, B (Yang, Bin)[ 1 ] ; Liu, M (Liu, Ming)[ 1 ] ; Chen, Y (Chen, Yong)[
關(guān)鍵字：Gold; Silver; Titanium silicalite-1; Photocatalysis; Propene epoxidation; Synergetic effect
論文來源：期刊
具體來源：CHINESE JOURNAL OF CATALYSIS
發(fā)表時(shí)間：2017年
Au-Ag bimetallic nanoparticle-supported microporous titanium silicalite-1 catalysts were prepared via a hydrothermal-immersion method, and their structures were examined. These materials serve as efficient catalysts for the photosynthesis of propylene oxide via the epoxidation of propene. The Au/Ag mass ratio and reaction temperature were demonstrated to have significant effects on the catalytic activity and selectivity of propylene oxide. The optimal formation rate (68.3 mu mol/g.h) and selectivity (52.3%) toward propylene oxide were achieved with an Au:Ag mass ratio of 4:1. Notably, the strong synergistic effect between Au and Ag resulted in superior photocatalysis of the bimetallic systems compared with those of the individual systems. A probable reaction mechanism was proposed based on the theoretical and experimental results. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.