1,8-Naphthyridine and 8-hydroxyquinoline modified Rhodamine B derivatives: “Turn-on” fluorescent and colorimetric sensors for Al3+ and Cu2+
作者：Yu, M. M.*; Yuan, R. L.; Shi, C. X.; Zhou, W.; Wei, L. H.; Li, Z. X.*
關鍵字：SELECTIVE FLUORESCENT; ALUMINUM ACCUMULATION; AQUEOUS-SOLUTION; HYBRID LIGAND; CHEMOSENSOR; IONS; PROBE; WATER; SCAFFOLD; ACID
論文來源：期刊
具體來源：Dyes Pigments 2013, 99, 887-894.
發表時間：2013年
Based on Rhodamine B, two Al3+/Cu2+-selective chemosensors were synthesized, which display a high selectivity for Al3+ and Cu2+ among environmentally and biologically relevant metal ions. A 1,8-Naphthyridine modified rhodamine derivative can detect Al3+ in ethanol with off-on fluorescence behavior, and detect Cu2+ in aqueous solution with colorimetric method. The 8-Hydroxyquinoline-based rhodamine sensor can detect Al3+ in ethanol with both off-on fluorescence and colorimetric methods. The detection mechanism involves a ring-opening process as a consequence of metal complex formation. Job''s plots and a time-of-flight mass spectral study indicated that each chemosensor chelated Al3+/Cu2+ with 1:1 stoichiometry. The binding of the chemosensors and Al3+/Cu2+ is chemically reversible by the addition of F-/EDTA solution, respectively.